Botryogen - Encyclopedia

    Class : Sulphates, chromates, molybdates
    Subclass : Hydrated sulphates
    Crystal system : Monoclinic
    Chemistry : MgFe(SO4)2OH 7H2O
    Rarity : Uncommon


Botryogen is a rather uncommon double sulphate of magnesium and iron, formed by the alteration of iron sulfides, especially in arid climates. Its name comes from the Greek botrus (cluster) and gennân (to generate) in allusion to the botryoidal shape of the discovery samples. It is part of a classic mineralogical procession to which other iron sulphates commonly belong (copiapite, jarosite, amarantite, fibroferrite, etc...), resulting like it from precipitation from "natural" sulfuric acid formed by reaction of surface water with iron sulphides. By changing the conditions of the environment (temperature, pH, oxidation-reduction potential) these sulphates are easily hydrolyzed into ferric hydroxides (goethite, limonite, etc...). Botryogen occurs mainly in botryoidal or reniform masses, in spherolites with a radiated texture, rarely in small striated prismatic crystals. Its color is light to dark orange-red.

Main photo : Botryogen from Fallun, Dalarna, Sweden © Peter Haas

Botryogen from Fallun, Dalarna, Sweden © OT. Ljostad
Botallackite from Libiola, Liguria, Italy © Gianfranco Ciccolini
Botryogen from Glen Echo Ravine, Ohio, USA © John Krygier
Botryogen from Huelva, Andalusia, Spain © Hervé Osana

Botryogen in the World

Botryogen is best known in the oxidation zone of the large copper-bearing porphyries of northern Chile : Chuquicamata, which produced rare millimetric crystals, and Alcaparrosa. It is also known in the sulphidic mass of Rammelsberg (Germany), and in several American deposits. It is reported in Italy, particularly on the Island of Elba, as well as in Fallun (Sweden), its discovery site.

Botryogen in France

In France, botryogen is reported in the antimony veins of Charbes (Bas-Rhin).

Twinning

No known twin for this mineral species.

Fakes and treatments

No fake inventories for this mineral species.



Hardness : 2 to 2.5
Density : 2.14
Fracture : Irregular to conchoidal
Trace : Brown-yellow



TP : Translucent to transparent
RI : 1.522 to 1.577
Birefringence : 0.055
Optical character : Biaxial +
Pleochroism : Visible
Fluorescence : None


Solubility : Water, hydrochloric acid

Magnetism : None
Radioactivity : None

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